You would find the (x,y) location of the colors produced by the new phosphors for maximum luminance (or intensity) and plot them on the chramticity diagram. The triangle given by these points define the monitor's color gamut. This can be compared to other monitors by drawing each monitor's color gamut (defined by their three phosphers) on the diagram, and comparing the areas of the triangles.
CMY: (1.0, 1.0, 1.0) - (0.2, 0.3, 0.8) = (0.8, 0.7, 0.2)
CMYK: CMY values as above. K is min(C, M, Y) = 0.2. The answer is, therefore, (0.8, 0.7, 0.2, 0.2)